Mäkelä, Mikko
- Institutionen för skogens biomaterial och teknologi, Sveriges lantbruksuniversitet
- Aalto-universitetet
Forskningsartikel2019Vetenskapligt granskadÖppen tillgång
Gomez Millan, Gerardo; Phiri, Josphat; Makela, Mikko; Maloney, Thad; Balu, Alina M.; Pineda, Antonio; Llorca, Jordi; Sixta, Herbert
The formation of furfural from xylose was investigated under heterogeneously catalyzed conditions with Starbon (R) 450-SO3H as a catalyst in a biphasic system. Experiments were performed based on a statistical experimental design. The variables considered were time and temperature. Starbon (R) 450-SO3H was characterized by scanning electron microscopy, N-2-physisorption, thermogravimetric analysis, diffuse reflectance infrared Fourier transform, Raman spectroscopy, pyridine titration and X-ray photoelectron spectroscopy. The results indicate that sulfonated Starbon (R) 450-SO3H can be an effective solid acid catalyst for furfural formation. A maximum furfural yield and selectivity of 70 mol% was achieved at complete xylose conversion under optimum experimental conditions. The present paper suggests that functionalized Starbon (R) 450-SO3H can be employed as an efficient solid acid catalyst that has significant hydrothermal stability and can be reused for several cycles to produce furfural from xylose.
Xylose; Furfural; Carbonized starch; Cyclopentyl methyl ether; Heterogeneous catalysis; Biorefinery
Applied Catalysis A: General
2019, Volym: 585, artikelnummer: 117180
Utgivare: ELSEVIER
Kemiska processer
DOI: https://doi.org/10.1016/j.apcata.2019.117180
https://res.slu.se/id/publ/101968